There was a thunderstorm at the Lambert-St. Louis Int'l airport on Aug 25, 2006. Let's look at the observations before, during, and after the thunderstorm.
This is the raw observation code, and I've edited values out to save space and for the sake of clarity.
Start of thunderstorm & rain...temperature is 26C, dewpoint is 19C--yields an relative humidty of 65%.
SPECI KSTL 251743Z 7SM -TSRA 26/19
Rain is getting ready to stop, it has rained for more than an hour at this point...temperature is 24C, dewpoint is 22C--yields a relative humidity of 89%.
METAR KSTL 251851Z 5SM -RA 24/22
Rain has stopped for 100 minutes or so...temp is 26C, dewpoint 21C--yields a relative humidity of 74%
METAR KSTL 252051Z 9SM 26/21
Now, this was an example during the middle of the day and afternoon. Relative humidity goes through a diurnal cycle and increases at night because the air temperature cools down to near the dew point.